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| diatomite |
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| opoka |
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| diatomite |
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| tubular
diatoms |
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| lepispheres |
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THE SILICA
FAMILY |
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Opaline
Silica |
| Many types
of earthy and dispersed forms of opaline
material come into this category. They may
form large deposits of white to off-white,
sometimes powdery, sometimes compact, material.
The best known of these types of deposits
are those known as Diatomite,
or diatomaceous earth. They may contain
a proportion of kaolinitic clay, when they
are termed opal claystone. The latter occurs
in large amounts in south eastern United
States, where it occurs in extensive bedded
deposits.
Opaline silica is
mined on a large scale for use, for example:
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in the ceramic
industry |
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as a filtration
agent |
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as
an absorbent |
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as a filler |
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for the manufacture
of dog and cat litter |
Similar deposits occur in
southern Russia, where the material is called
'opoka',
and in western Europe, where it is variously
termed tripoli, gaize, kieselguhr or moler
depending on its nature and country of origin
footnote.
Soft earthy deposits are often composed
of the skeletons of minute marine or fresh
water organisms called diatoms.
Diatomite,
which is soft and of low density, is a good
insulating material, and is widely used
for this purpose. It is used as well for
the manufacture of lightweight refractories,
as an absorbent, filler and filtration agent.
Large deposits occur in eastern Australia,
and are described by Irene Crespin (R1548).
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In parts
of the deep oceans extensive deposits of
siliceous sediments occur. These are often
composed of radiolaria and diatoms which
are minute organisms which have silica skeletons;
these fall to the ocean floor on the death
of the organisms, and, over long periods
of time, build up extensive layers. In recent
years scientists studying deep sea deposits
have also found large deposits of other
types of fine opaline material in cores
from deep ocean drilling. The opal in these
samples has often recrystallised in part,
forming rosettes
of tiny platelets of crystals of opaline
material; these structures have been termed
'lepispheres'. On land, these materials
are represented by, often large, deposits
of fine grained silica such as diatomite,
tripoli or opoka. More details on these
materials will be found in later sections.
Plants may also secrete opaline silica in
their cells and other structures, and, on
the death and decomposition of the plant
the silica is released into the soil as
minute spicules or other forms. Certain
plants, such as the equisitalia ('horse
tails') and the myrtacae, are particularly
rich in silica; the ash after burning some
of these plants has been shown to contain
as much as 93% silica.
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| Evidence of the presence
of this opaline material is sometimes found
in the form of large pieces of so-called
'haystack glass', formed on the accidental
burning of haystacks(pb46). The potash and
other inorganic elements in the hay combine
and melt in the heat of the burning hay
to form lumps of glassy material.
A dramatic example of this may be found
in an article by George Baker (R0363),
where he describes the results of the burning
of two haystacks in western Victoria. He
found that some 16 tonnes of hay-silica
glass were produced from some 330 tonnes
of hay from pasture grass.
When plants such as grasses decay in the
soil, the opal in their cells is released
as minute spicules and other transparent
particles, accumulating in the soil. This
can be readily seen with an optical microscope.
The difference in character between the
silica-rich grass and hay ash, and the silica-poor
ash from, for example, softwoods, is known
and used by the traditional art potter.
Ash is commonly used for special effects
in ceramic glazes; the hay ash (high in
silica) is known as 'hard ash', while the
low silica ash is termed 'soft ash'. |
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